E. Marten

You need to use WordPress SEO by Yoast (Props to him!)
Adds “More Sitemaps” to your WordPress SEO Settings. If you are using a second WordPress-Installation in a subdirectory, you can now easily add the second Sitemap into the main one.
If you are using a second WordPress-installation in a subdirectory and want it to be fully integrated it into your main site to prevend struggeling with two or more Sitemaps in your Webmastertools, 
you can easily integrate more sitemaps into your main one. (sitemap_index.xml) 
The Plugin adds your second and third (aso) sitemap into the main sitemap and tooks care about the modification date automatically!
Thanks to Joost de Valk!

IsSiY (Include second Sitemap into Yoast) WordPress SEO Extension

Adds "More Sitemaps" to your Wordpress SEO Settings. Include differen sitemaps to your sitemap_index.xml

Lee Willis

This plugin automatically adds products and categories from the WP E-Commerce plugin to your XML sitemap to help search engines discover your shop.

WP Shopping Cart XML Sitemap

Add XML sitemap entries for WP E-Commerce categories and products

IsSiY (Include second Sitemap into Yoast) WordPress SEO Extension vs WP Shopping Cart XML Sitemap