crimson090

Adds buttons to the Text (HTML) edit which generate Markdown syntax. These buttons serve as a great introduction to 
users who are new to Markdown, as well as shortcuts for more experienced users. The buttons include:
<ul>
<li>Bold</li>
<li>Italic</li>
<li>Blockquote</li>
<li>Link</li>
<li>Code</li>
<li>Table</li>
<li>Headers</li>
<li>Help (links to external Github Markdown guide)</li>
</ul>
This plugin does not modify the Visual editor, as that editor is not ideal for writing Markdown in. It’s recommended you disable 
the Visual editor entirely to enforce using Markdown.
Note that this plugin does not render Markdown. You should use a plugin (such as Jetpack Markdown) to render markdown in your theme.

MarkdownBar

Adds a toolbar of buttons to the Text (HTML) edit which generate Markdown syntax

Stephen Harris

This plugin allows you to write posts (of any post type) using the Markdown syntax. The plugin converts the Markdown into HTML prior to saving the post. When editing a post, the plugin converts it back into Markdown syntax.
The plugin also allows you to enable Markdown in comments and bbPress forums. In these instances the plugin adds a toolbar, and preview of the processed Markdown with <a href="http://code.google.com/p/google-code-prettify/" rel="nofollow ugc">Prettify</a> syntax highlighter applied (similiar to that used in the Stack Exchange websites such as <a href="http://wordpress.stackexchange.com/" rel="nofollow ugc">WordPress Stack Exchange</a>).
WP-Markdown stores the processed HTML, so deactivating the plugin will not affect your posts, comments or bbPress forums.

WP-Markdown

Version 1.5.1 of the plugin works almost perfectly.
I'm just waiting for the upcoming 1.6 update (which is in alpha on GitHub) to be pushed, so I can use GitHub Flavor-style codeblocks specifying the exact language.



Waiting for 1.6

Allows Markdown to be enabled in posts, comments and bbPress forums.

MarkdownBar vs WP-Markdown