WP-Validate indexes your site, collecting all the blog posts, pages and other published content, and submits it to the W3C’s HTML Validator, which then returns the response.
WP-Validate then lists the valid pages, and the invalid pages, with a link to the specific validator URL.

WP-Validate

WP-Validate collects all the pages on your site and runs them through the W3C's HTML Validator.

Nikoya

Check the doctype validity using W3c validator (html , xhtml , … ) when creating or updating page / post / custom post type and show the result in backend 
It show the result in back-end in sortable column, a link is add to the w3c for all file to help you to correct html error.
Very easy to see if a post / page is valid or not.
This plugin can check the W3C validity of your page / post or custom post type even if the site is not accessible from the Internet (if you work on local system for example)

(x)html easy validator

Check the doctype validity using W3c validator (html , xhtml , ... ) when creating or updating  page / post / custom post type and show the result in  …

WP-Validate vs (x)html easy validator